A heterobimetallic cumulenic μ-carbido complex
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Hill, Anthony; Watson, Lachlan
Description
The reaction [W(CSe)(CO)2(Tp*)]NEt4 (Tp* = hydrotris(dimethylpyrazolyl)-borate) with N-methyl-N-nitroso-4-toluenesulfonamide affords the nitrosyl complex [W(CSe)(CO)(NO)(Tp*)] which on treatment with excess [Re(THF)(CO)2(g-C5H5)] affords the cumuenic l-carbido complex [WRe(l-C)(CO)3(NO)(Tp*)(g-C5H5)] in addition to the l-selenido complex [Re2(l-Se)(CO)4(g-C5H5)2].
Collections | ANU Research Publications |
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Date published: | 2020 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/209274 |
Source: | Chemical Communications |
DOI: | 10.1039/c9cc08172k |
Access Rights: | Open Access |
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10.1039_c9cc08172k.pdf | 5.4 MB | Adobe PDF | ![]() |
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