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A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds

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Cullen, Duncan; Gardiner, Michael; White, Nicholas

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A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.

dc.contributor.authorCullen, Duncan
dc.contributor.authorGardiner, Michael
dc.contributor.authorWhite, Nicholas
dc.date.accessioned2020-09-02T23:52:41Z
dc.date.available2020-09-02T23:52:41Z
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/209269
dc.description.abstractA crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.rights© The Royal Society of Chemistry 2019
dc.sourceChemical Communications
dc.titleA three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume55
dc.date.issued2019
local.identifier.absfor030505 - Physical Organic Chemistry
local.identifier.absfor030302 - Nanochemistry and Supramolecular Chemistry
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationu5786633xPUB1596
local.type.statusPublished Version
local.contributor.affiliationCullen, Duncan, College of Science, ANU
local.contributor.affiliationGardiner, Michael, College of Science, ANU
local.contributor.affiliationWhite, Nicholas, College of Science, ANU
local.description.embargo2037-12-31
local.identifier.essn1364-548X
local.bibliographicCitation.issue80
local.bibliographicCitation.startpage12020
local.bibliographicCitation.lastpage12023
local.identifier.doi10.1039/c9cc06707h
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2020-05-10T08:18:08Z
local.identifier.thomsonIDWOS:000496529500005
CollectionsANU Research Publications

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