A three dimensional hydrogen bonded organic framework assembled through antielectrostatic hydrogen bonds
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Cullen, Duncan; Gardiner, Michael
; White, Nicholas
Description
A crystalline 3D hydrogen bonded framework is assembled in water from tetrahedral tetraamidinium cations and antielectrostatically hydrogen bonded bicarbonate dimers. The framework forms in water, and represents a clear demonstration of the potency of these anti-Coulombic hydrogen bonds. Gentle heating of the framework (50 °C) releases CO2 and water to give the neutral tetraamidine compound.
Collections | ANU Research Publications |
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Date published: | 2019 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/209269 |
Source: | Chemical Communications |
DOI: | 10.1039/c9cc06707h |
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01_Cullen_A_three_dimensional_hydrogen_2019.pdf | 2.25 MB | Adobe PDF | Request a copy |
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