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Toward a Quantitative Description of Radical Photoinitiator Structure–Reactivity Correlations

Frick, Elena; Schweigert, Caroline; Noble, Dr Benjamin; Ernst, Hanna A.; Lauer, Andrea; Liang, Yu; Voll, Dominik; Coote, Michelle; Unterreiner, Andreas-Neil; Barner-Kowollik, Christopher


The fundamental influence of the structure and substitution of radical photoinitiators was investigated via a trifold combination of pulsedlaser polymerization with subsequent electrospray-ionization mass spectrometry (PLP-ESI-MS), femtosecond transient absorption (fs-TA) spectroscopy, and quantum chemistry. For the first time, a library of benzoin-derived photoinitiators with varied substitution patterns was synthesized. In the PLPESI-MS study, different photoinitiators were compared...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Macromolecules
DOI: 10.1021/acs.macromol.5b02336
Access Rights: Open Access


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