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A Dirhoda-Heterocyclic Carbene

Barnett, Harrison; Hill, Anthony


The linear m-carbido complex [Rh2(m-C)Cl2- (dppm)2] (dppm = bis(diphenylphosphino)methane) reacts with dimethylacetylene dicarboxylate (DMAD) to afford [Rh2(m-C)(m-DMAD)Cl2(dppm)2], which features a bent RhCRh linkage (124.78) that might be described as a dirhoda-heterocyclic carbene, as demonstrated by coordination to further metal centers.

CollectionsANU Research Publications
Date published: 2020
Type: Journal article
Source: Angewandte Chemie International Edition
DOI: 10.1002/anie.201912650
Access Rights: Open Access


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