Polymerization of Vinyl Chloride at Ambient Temperature Using Macromolecular Design via the Interchange of Xanthate: Kinetic and Computational Studies
Reversible deactivation radical polymerization of vinyl chloride (VC) by methyl (ethoxycarbonothioyl)sulfanyl acetate (MEA)-mediated macromolecular design via the interchange of xanthate (MADIX) polymerization at ambient temperature is reported. The polymerization system was studied using two conventional radical initiators (having very distinct half-life times at room temperature). The system was optimized regarding the nature of the solvent, the monomer concentration, the...[Show more]
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