The Synthesis, Structural Characterisation and Chemical Manipulation of the [6+3] Cycloadduct Derived from alpha-Tropolone O-Methyl Ether and Trimethylenemethane
The title bicyclic system 3, the adduct arising from the formal [6+3] cycloaddition of α‐tropolone O‐methyl ether (1) and trimethylenemethane (2), has been prepared and subject to single‐crystal X‐ray analysis. The chemical manipulation of adduct 3 in a range of ways is reported, including through acid‐catalysed rearrangement of the derived mono‐oxide to give the bicyclo[4.3.1]undecane 21.
|Collections||ANU Research Publications|
|Source:||Asian Journal of Organic Chemistry|
|Access Rights:||Open Access|
|The Synthesis Structural Characterisation.pdf||1.65 MB||Adobe PDF|
Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.