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Switching radical stability by pH- induced orbital conversion

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Gryn'ova, Ganna; Marshall, David L; Blanksby, Stephen James; Coote, Michelle

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In most radicals the singly occupied molecular orbital (SOMO) is the highest-energy occupied molecular orbital (HOMO); however, in a small number of reported compounds this is not the case. In the present work we expand significantly the scope of this phe

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
URI: http://hdl.handle.net/1885/20714
Source: Nature Chemistry
DOI: 10.1038/nchem.1625

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