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Switching radical stability by pH- induced orbital conversion

Gryn'ova, Ganna; Marshall, David L; Blanksby, Stephen James; Coote, Michelle


In most radicals the singly occupied molecular orbital (SOMO) is the highest-energy occupied molecular orbital (HOMO); however, in a small number of reported compounds this is not the case. In the present work we expand significantly the scope of this phe

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Nature Chemistry
DOI: 10.1038/nchem.1625


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