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Propargylidyne and tricarbido complexes

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Manzano, Richard; Hill, Anthony

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Propargylidynes, LnM ≡ C-C ≡ CR, represent a special sub-class of carbyne complexes in which metal-carbon and carbon-carbon triple bonds are conjugated. Tricarbido complexes may be considered as a sub-class of propargylidynes in which the substituent “R” is a second metal center. In this review we comprehensively survey the chemistry of propargylidyne and tricarbido complexes up to October 2018, including points where their respective chemistries converge.

dc.contributor.authorManzano, Richard
dc.contributor.authorHill, Anthony
dc.date.accessioned2020-07-21T02:16:15Z
dc.identifier.issn0065-3055
dc.identifier.urihttp://hdl.handle.net/1885/206437
dc.description.abstractPropargylidynes, LnM ≡ C-C ≡ CR, represent a special sub-class of carbyne complexes in which metal-carbon and carbon-carbon triple bonds are conjugated. Tricarbido complexes may be considered as a sub-class of propargylidynes in which the substituent “R” is a second metal center. In this review we comprehensively survey the chemistry of propargylidyne and tricarbido complexes up to October 2018, including points where their respective chemistries converge.
dc.format.extent69 pages
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherElsevier
dc.rights© 2019 Elsevier Ltd
dc.sourceAdvances in Organometallic Chemistry
dc.subjectCarbon-wires, Carbyne, Alkylidyne, Propargylidyne, Bimetallic, Clusters, Tricarbido
dc.titlePropargylidyne and tricarbido complexes
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume72
dc.date.issued2019
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationu5786633xPUB1894
local.publisher.urlhttps://www.elsevier.com/
local.type.statusPublished Version
local.contributor.affiliationManzano, Richard, College of Science, The Australian National University
local.contributor.affiliationHill, Anthony, College of Science, The Australian National University
local.description.embargo2037-12-31
local.bibliographicCitation.startpage103
local.bibliographicCitation.lastpage171
local.identifier.doi10.1016/bs.adomc.2019.05.001
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciences
dc.date.updated2020-04-12T08:21:56Z
local.identifier.thomsonIDWOS:000486616800004
CollectionsANU Research Publications

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