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Auriferous alkynylselenolatoalkylidynes

Frogley, Benjamin; Hill, Anthony; Onn, Chee Sheng


The reaction of alkynylselenolatoalkylidynes [W([triple bond, length as m-dash]CSeC[triple bond, length as m-dash]CR)(CO)2(Tp*)] (R = SiMe3, SiiPr3, Ph, p-tolyl, tBu, CPh3, SiPh3, GePh3; Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with [AuCl(L)] (L = tetrahydrothiophene, SMe2) readily furnishes heterobimetallic complexes [WAu(μ-CSeC[triple bond, length as m-dash]CR)Cl(CO)2(Tp*)] where gold(I) chloride coordinates to the tungsten–carbon multiple bond. Alternatively, desilylation of the...[Show more]

CollectionsANU Research Publications
Date published: 2019-07-04
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c9dt02314c
Access Rights: Open Access


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