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Open Pentiptycene Networks Assembled through Charge-Assisted Hydrogen Bonds

Boer, Stephanie; Wang, Pei-Xi; MacLachlan, Mark J.; White, Nicholas


A series of hydrogen-bonded networks was prepared incorporating ditopic, tritopic, or tetratopic polyamidinium tectons and linear pentiptycene dicarboxylates. The ditopic amidinium forms a 1D hydrogen bonded chain when combined with the pentiptycene tecton, while the tritopic trigonal planar amidinium tecton forms a 2D honeycomb network. A tetratopic amidinium tecton forms a 3D diamondoid network, which is 32-fold interpenetrated, tied for the highest degree of interpenetration observed for a...[Show more]

CollectionsANU Research Publications
Date published: 2019-07-24
Type: Journal article
Source: Crystal Growth & Design
DOI: 10.1021/acs.cgd.9b00801
Access Rights: Open Access


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