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Reversal of regioselectivity and enhancement of rates of nitrile oxide cycloadditions through transient attachment of dipolarophiles to cyclodextrins

Barr, Lorna; Lincoln, Stephen F; Easton, Christopher


The reactions of nitrile oxides with monosubstituted dipolarophiles, such as propiolamide, typically afford proportionally 80% or more of the 3,5-disubstituted cycloadducts. By contrast, the reactions of 6 A-deoxy-6A-propynamido-β-cyclodextrin with 4-ter

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Chemistry, A European Journal
DOI: 10.1002/chem.200600627


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