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Interrogation of the Effect of Polymorphism of a Metal-Organic Framework Host on the Structure of Embedded Pd Guest Nanoparticles

Butson, Joshua; Kim, Hyunjeong; Murugappan, Krishnan; Saunders, Martin; Buckley, Craig Edward; Silvester, Debbie S.; Szilágyi, Petra A.


Metal‐organic frameworks (MOFs) are very promising host materials for nanoscale guest materials. However, some MOFs such as MIL‐53 are known to undergo phase transitions which can complicate the guest particle size control. In this study, Pd nanoparticles embedded in Al‐MIL‐53 were synthesised via (a) electrodeposition and (b) gas‐phase reduction. A thorough structural investigation revealed that each synthesis method most likely favoured a different phase of Al‐MIL‐53, presenting the...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: ChemPhysChem
DOI: 10.1002/cphc.201801037


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