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Critical role of the coupling between the octahedral rotation and A-site ionic displacements in PbZrO3-based antiferroelectric materials investigated by in situ neutron diffraction

Lu, Teng; Studer, Andrew J.; Yu, Dehong; Withers, Ray; Feng, Yujun; Chen, Hua; Islam, S. S.; Xu, Zhuo; Liu, Yun

Description

This in situ neutron-diffraction study on antiferroelectric (AFE) Pb0.99(Nb0.02Zr0.65Sn0.28Ti0.05)O3 polycrystalline materials describes systematic structural and associated preferred orientation changes as a function of applied electric field and temperature. It is found that the pristine AFE phase can be poled into the metastable ferroelectric (FE) phase at room temperature. At this stage, both AFE and FE phases consist of modes associated with octahedral rotation and A-site ionic...[Show more]

CollectionsANU Research Publications
Date published: 2017
Type: Journal article
URI: http://hdl.handle.net/1885/202143
Source: Physical Review B
DOI: 10.1103/PhysRevB.96.214108
Access Rights: Open Access

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