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Synthesis and ligand substitution reactions of κ⁴-B,S,S′,S′′-ruthenaboratranes

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Foreman, Mark R.; Hill, Anthony; Ma, Chenxi; Tshabang, Never; White, Andrew J P

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A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S′,S′′-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S′,S′′-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].

dc.contributor.authorForeman, Mark R.
dc.contributor.authorHill, Anthony
dc.contributor.authorMa, Chenxi
dc.contributor.authorTshabang, Never
dc.contributor.authorWhite, Andrew J P
dc.date.accessioned2020-02-19T03:11:26Z
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/201782
dc.description.abstractA range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S′,S′′-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S′,S′′-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].
dc.description.sponsorshipThis work was supported by the Australian Research Council (DP170102695).
dc.format.extent11 pages
dc.format.mimetypeapplication/pdf
dc.language.isoen_AU
dc.publisherRoyal Society of Chemistry
dc.rights© The Royal Society of Chemistry 2019
dc.sourceDalton Transactions
dc.titleSynthesis and ligand substitution reactions of κ⁴-B,S,S′,S′′-ruthenaboratranes
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume48
dcterms.dateAccepted2018-11-23
dc.date.issued2019
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor030204 - Main Group Metal Chemistry
local.identifier.ariespublicationu3102795xPUB2301
local.publisher.urlhttps://www.rsc.org/
local.type.statusAccepted Version
local.contributor.affiliationForeman, Mark R., Chalmers University of Technology
local.contributor.affiliationHill, Anthony, College of Science, The Australian National University
local.contributor.affiliationMa, Chenxi, College of Science, The Australian National University
local.contributor.affiliationTshabang, Never, College of Science, The Australian National University
local.contributor.affiliationWhite, Andrew J P, Imperial College London
dc.relationhttp://purl.org/au-research/grants/arc/DP170102695
local.identifier.essn1477-9234
local.bibliographicCitation.issue1
local.bibliographicCitation.startpage209
local.bibliographicCitation.lastpage219
local.identifier.doi10.1039/c8dt04278k
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciences
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2023-02-05T07:17:23Z
local.identifier.scopusID2-s2.0-85058724339
local.identifier.thomsonID4.53681E+11
dcterms.accessRightsOpen Access
dc.provenancehttps://v2.sherpa.ac.uk/id/publication/18010..."The Accepted Version can be archived in a Non-Commercial Repository. 12 months embargo" from SHERPA/RoMEO site (as at 11/12/2020).
CollectionsANU Research Publications

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