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Synthesis and ligand substitution reactions of κ⁴-B,S,S′,S′′-ruthenaboratranes

Foreman, Mark R.; Hill, Anthony; Ma, Chenxi; Tshabang, Never; White, Andrew J P


A range of ruthenaboratranes of the form [Ru(CO)L{κ4-B,S,S′,S′′-B(mt)3}] (mt = N-methylmercaptoimidazolyl) have been prepared either by substitution of the PPh3 ligand in [Ru(CO)(PPh3){κ4-B,S,S′,S′′-B(mt)3}] by L (L = PMe2Ph, PMe3, P(OMe)3, P(OEt)3, P(OPh)3) or reactions of [RuCl(R)(CO)Ln] (R = Ph, CH[double bond, length as m-dash]CHPh; n = 2, L = PCy3; n = 3, L = P(OMe)3, PMe2Ph) with Na[HB(mt)3].

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c8dt04278k
Access Rights: Open Access


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