Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes
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Description
The reactions of [RuCl(R)(CO)(PPh3)2] (R = CH[double bond, length as m-dash]CHPh, Ph) with Na[H2B(mt)2] (mt = N-methyl-2-mercaptoimidazolyl) transiently provide [Ru(R)(CO)(PPh3){κ3-H,S,S′-H2B(mt)2}] which each evolve to the ruthenaboratrane [Ru(CO)(PPh3)2{κ3-B,S,S′-BH(mt)2}](Ru→B)8. The phosphine ligands may be selectively replaced to provide the complexes [Ru(CO)(L)(PPh3){κ3-B,S,S′-BH(mt)2}] (L = CO, PMe2Ph) and [Ru(CO)L2{κ3-B,S,S′-BH(mt)2}] (L = PMe2Ph, P(OMe)3, L2 = Z-Ph2PCH[double bond,...[Show more]
Collections | ANU Research Publications |
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Date published: | 2019 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/201758 |
Source: | Dalton Transactions |
DOI: | 10.1039/c8dt04813d |
Access Rights: | Open Access |
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Methimazolyl Based Diptych.pdf | 4.58 MB | Adobe PDF | ![]() |
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