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Methimazolyl based diptych bicyclo-[3.3.0]-ruthenaboratranes

Ma, Chenxi; Hill, Anthony


The reactions of [RuCl(R)(CO)(PPh3)2] (R = CH[double bond, length as m-dash]CHPh, Ph) with Na[H2B(mt)2] (mt = N-methyl-2-mercaptoimidazolyl) transiently provide [Ru(R)(CO)(PPh3){κ3-H,S,S′-H2B(mt)2}] which each evolve to the ruthenaboratrane [Ru(CO)(PPh3)2{κ3-B,S,S′-BH(mt)2}](Ru→B)8. The phosphine ligands may be selectively replaced to provide the complexes [Ru(CO)(L)(PPh3){κ3-B,S,S′-BH(mt)2}] (L = CO, PMe2Ph) and [Ru(CO)L2{κ3-B,S,S′-BH(mt)2}] (L = PMe2Ph, P(OMe)3, L2 = Z-Ph2PCH[double bond,...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c8dt04813d
Access Rights: Open Access


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