Isoselenocarbonyl complexes
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Cade, Ian; Hill, Anthony; McQueen, Caitlin
Description
The salt elimination reactions of [NEt4][Mo(CSe)(CO)2(Tp*)] ([NEt4][2], Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with a range of metal halide complexes (ClMLn) have been investigated as a possible route to isoselenocarbonyl complexes [Mo(CSeMLn)(CO)2(Tp*)]. Thus the reactions of [NEt4][2] with [RuCl(L)2(η-C5R5)] provide molybdenum–ruthenium derivatives [Mo{CSeRu(L)2(η-C5R5)}(CO)2(Tp*)] (L = PPh3, R = H 4, L = CO, R = Me 5), both of which were structurally characterised. The...[Show more]
dc.contributor.author | Cade, Ian | |
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dc.contributor.author | Hill, Anthony | |
dc.contributor.author | McQueen, Caitlin | |
dc.date.accessioned | 2020-02-18T03:25:59Z | |
dc.identifier.issn | 1477-9226 | |
dc.identifier.uri | http://hdl.handle.net/1885/201756 | |
dc.description.abstract | The salt elimination reactions of [NEt4][Mo(CSe)(CO)2(Tp*)] ([NEt4][2], Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with a range of metal halide complexes (ClMLn) have been investigated as a possible route to isoselenocarbonyl complexes [Mo(CSeMLn)(CO)2(Tp*)]. Thus the reactions of [NEt4][2] with [RuCl(L)2(η-C5R5)] provide molybdenum–ruthenium derivatives [Mo{CSeRu(L)2(η-C5R5)}(CO)2(Tp*)] (L = PPh3, R = H 4, L = CO, R = Me 5), both of which were structurally characterised. The molybdenum–iron derivative [Mo{CSeFe(CO)2(η-C5H5)}(CO)2(Tp*)] (6) was obtained from [NEt4][2] and [FeCl(CO)2(η-C5H5)] however its formulation currently rests on spectroscopic and microanalytical data. The reaction of [NEt4][2] with [RuH(NCMe)(CO)2(PPh3)2]PF6 affords the structurally characterised hydrido-isoselenocarbonyl complex [Mo{CSeRuH(CO)2(PPh3)2}(CO)2(Tp*)] (7) with no indication of coupling of the hydride and selenocarbonyl ligand. | |
dc.description.sponsorship | This work was supported by the Australian Research Council (DP110101611 and DP170102695). | |
dc.format.mimetype | application/pdf | |
dc.language.iso | en_AU | |
dc.publisher | Royal Society of Chemistry | |
dc.rights | © The Royal Society of Chemistry 2019 | |
dc.source | Dalton Transactions | |
dc.title | Isoselenocarbonyl complexes | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 48 | |
dc.date.issued | 2019 | |
local.identifier.absfor | 039904 - Organometallic Chemistry | |
local.identifier.absfor | 030207 - Transition Metal Chemistry | |
local.identifier.absfor | 030204 - Main Group Metal Chemistry | |
local.identifier.ariespublication | u3102795xPUB2217 | |
local.publisher.url | https://www.rsc.org/ | |
local.type.status | Accepted Version | |
local.contributor.affiliation | Cade, Ian, College of Science, ANU | |
local.contributor.affiliation | Hill, Anthony, College of Science, ANU | |
local.contributor.affiliation | McQueen, Caitlin, College of Science, ANU | |
dc.relation | http://purl.org/au-research/grants/arc/DP110101611 | |
dc.relation | http://purl.org/au-research/grants/arc/DP170102695 | |
local.bibliographicCitation.issue | 6 | |
local.bibliographicCitation.startpage | 2000 | |
local.bibliographicCitation.lastpage | 2012 | |
local.identifier.doi | 10.1039/c8dt04947e | |
local.identifier.absseo | 970102 - Expanding Knowledge in the Physical Sciences | |
local.identifier.absseo | 970103 - Expanding Knowledge in the Chemical Sciences | |
dc.date.updated | 2019-11-25T07:34:07Z | |
local.identifier.thomsonID | 4.57874E+11 | |
dcterms.accessRights | Open Access | |
dc.provenance | http://sherpa.ac.uk/romeo/issn/1477-9226/..."author can archive post-print (ie final draft post-refereeing). 12 months embargo" from SHERPA/RoMEO site (as at 27/02/2020). | |
Collections | ANU Research Publications |
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Isoselenocarbonyl Complexes.pdf | 5.2 MB | Adobe PDF |
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