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Isoselenocarbonyl complexes

Cade, Ian; Hill, Anthony; McQueen, Caitlin


The salt elimination reactions of [NEt4][Mo(CSe)(CO)2(Tp*)] ([NEt4][2], Tp* = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with a range of metal halide complexes (ClMLn) have been investigated as a possible route to isoselenocarbonyl complexes [Mo(CSeMLn)(CO)2(Tp*)]. Thus the reactions of [NEt4][2] with [RuCl(L)2(η-C5R5)] provide molybdenum–ruthenium derivatives [Mo{CSeRu(L)2(η-C5R5)}(CO)2(Tp*)] (L = PPh3, R = H 4, L = CO, R = Me 5), both of which were structurally characterised. The...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
Source: Dalton Transactions
DOI: 10.1039/c8dt04947e
Access Rights: Open Access


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