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Corrected structure of natural hyacinthacine c 1 via total synthesis

Carroll, Anthony W; Willis, Anthony; Hoshino, Masako; Pyne, Stephen G

Description

Hyacinthacines C1 and C4 are natural products that were isolated from Hyacinthoides non-scripta and Scilla socialis in 1999 and 2007, respectively. Despite their different 1H NMR and 13C NMR spectroscopic data, these compounds have been assigned the same structures, including absolute configurations. This work details the total synthesis of natural (+)-hyacinthacine C1, whose structure is confirmed as being the C-6 epimer of that reported. The synthetic strategy focused on inverting the...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
URI: http://hdl.handle.net/1885/196870
Source: Journal of Natural Products
DOI: 10.1021/acs.jnatprod.8b00879

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