Ti02-Doped Zirconia: Crystal Structure, Monoclinic-Tetragonal Phase Transition, and the New Tetragonal Compound Zr3Ti08
Zirconia samples with up to 27 mol% TiO2 were synthesized at low and elevated pressures, significantly extending the range of ZrO 2-TiO2 solid solution compared with previous crystal structure studies of monoclinic and tetragonal zirconia (<17.5 mol%). Crystal structure data collected by powder X-ray diffraction (XRD) at ambient conditions reveal that the solid solution of TiO2 in monoclinic zirconia (baddeleyite structure, P21/c) is limited to about 25 mol%, where the tetragonal compound...[Show more]
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|Source:||Journal of the American Ceramic Society|
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