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1,1-Bis(N-methylimidazole)-2-(trimethylsilyl)-1-boracyclohexa-1,4-diene chloride: a stable intermediate or tangent en route to 1-(N-methylimidazole)borabenzene?

Cade, Ian; Hill, Anthony

Description

The reaction of 1-chloro-2-(trimethylsilyl)-1-boracylohexa-2,5-diene (1) with N-methylimidazole (NMI) results not in the anticipated borabenzene adduct [(NMI)→BC5H5] (3) but rather the title imidazole-stabilized cyclic boronium salt [(NMI)2BC5H5SiMe3-2]

dc.contributor.authorCade, Ian
dc.contributor.authorHill, Anthony
dc.date.accessioned2015-12-07T22:19:48Z
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/1885/19516
dc.description.abstractThe reaction of 1-chloro-2-(trimethylsilyl)-1-boracylohexa-2,5-diene (1) with N-methylimidazole (NMI) results not in the anticipated borabenzene adduct [(NMI)→BC5H5] (3) but rather the title imidazole-stabilized cyclic boronium salt [(NMI)2BC5H5SiMe3-2]
dc.publisherAmerican Chemical Society
dc.sourceJournal of the American Chemical Society
dc.subjectKeywords: En-route; Methylimidazole; N-methylimidazole; Trimethylsilyl; Chlorine compounds; Olefins; Reaction intermediates
dc.title1,1-Bis(N-methylimidazole)-2-(trimethylsilyl)-1-boracyclohexa-1,4-diene chloride: a stable intermediate or tangent en route to 1-(N-methylimidazole)borabenzene?
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume31
dc.date.issued2012
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu5072968xPUB8
local.type.statusPublished Version
local.contributor.affiliationCade, Ian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue5
local.bibliographicCitation.startpage2112
local.bibliographicCitation.lastpage2115
local.identifier.doi10.1021/om300002y
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T11:34:08Z
local.identifier.scopusID2-s2.0-84858116351
local.identifier.thomsonID000301331200063
CollectionsANU Research Publications

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