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Rate coefficients for intramolecular homolytic substitution of oxyacyl radicals at sulfur

Aitken, Heather; Horvat, Sonia; Coote, Michelle; Lin, Ching-Yeh; Schiesser, Carl


It is predicted on the basis of ab initio and density functional calculations that intramolecular homolytic substitution of oxyacyl radicals at the sulfur atom in ω-alkylthio-substituted radicals do not involve hypervalent intermediates. With tert-butyl

CollectionsANU Research Publications
Date published: 2013
Type: Journal article
Source: Australian Journal of Chemistry
DOI: 10.1071/CH12477


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