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Preparation, Structure, and Reactivity of Dipalladium(I) Complexes Containing the Carbanion 2?C6F4PPh2: Coexistence of Distinct, Noninterconverting Head-to-Head [Dipalladium(0/II)] and Head-to-Tail [Dipalladium(I)] Species

Bhargava, Suresh Kumar; Priver, Steven H; Willis, Anthony; Bennett, Martin

Description

Comproportionation of trans-[Pd(κ 2-2-C 6F 4PPh 2) 2] with [PdL 4] (L = PPh 3, AsPh 3) gives metal-metal-bonded dipalladium(I) complexes [Pd 2I(μ-2-C 6F 4PPh 2) 2(L) 2] [L = PPh 3 (5), AsPh 3 (6)] in which the bridging ligands adopt a head-to-tail arran

dc.contributor.authorBhargava, Suresh Kumar
dc.contributor.authorPriver, Steven H
dc.contributor.authorWillis, Anthony
dc.contributor.authorBennett, Martin
dc.date.accessioned2015-12-07T22:19:23Z
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/19318
dc.description.abstractComproportionation of trans-[Pd(κ 2-2-C 6F 4PPh 2) 2] with [PdL 4] (L = PPh 3, AsPh 3) gives metal-metal-bonded dipalladium(I) complexes [Pd 2I(μ-2-C 6F 4PPh 2) 2(L) 2] [L = PPh 3 (5), AsPh 3 (6)] in which the bridging ligands adopt a head-to-tail arran
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Binding modes; Bridging ligands; Dinuclear; In-situ; Iodobenzene; Metal atoms; Metal-metal distances; Metal-metal interactions; Methyl complexes; Methyl iodide; Mixed-valent; Oxidative additions; Palladium complexes; Reductive elimination; tert-Butyl isoc
dc.titlePreparation, Structure, and Reactivity of Dipalladium(I) Complexes Containing the Carbanion 2?C6F4PPh2: Coexistence of Distinct, Noninterconverting Head-to-Head [Dipalladium(0/II)] and Head-to-Tail [Dipalladium(I)] Species
dc.typeJournal article
local.description.notesImported from ARIES
local.identifier.citationvolume31
dc.date.issued2012
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu8302325xPUB7
local.type.statusPublished Version
local.contributor.affiliationBhargava, Suresh Kumar, RMIT University
local.contributor.affiliationPriver, Steven H, RMIT University
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBennett, Martin, College of Physical and Mathematical Sciences, ANU
local.description.embargo2037-12-31
local.bibliographicCitation.issue15
local.bibliographicCitation.startpage5561
local.bibliographicCitation.lastpage5572
local.identifier.doi10.1021/om300525p
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
dc.date.updated2016-02-24T11:39:31Z
local.identifier.scopusID2-s2.0-84864984643
local.identifier.thomsonID000307422200040
CollectionsANU Research Publications

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