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Preparation, Structure, and Reactivity of Dipalladium(I) Complexes Containing the Carbanion 2?C6F4PPh2: Coexistence of Distinct, Noninterconverting Head-to-Head [Dipalladium(0/II)] and Head-to-Tail [Dipalladium(I)] Species

Bhargava, Suresh Kumar; Priver, Steven H; Willis, Anthony; Bennett, Martin

Description

Comproportionation of trans-[Pd(κ 2-2-C 6F 4PPh 2) 2] with [PdL 4] (L = PPh 3, AsPh 3) gives metal-metal-bonded dipalladium(I) complexes [Pd 2I(μ-2-C 6F 4PPh 2) 2(L) 2] [L = PPh 3 (5), AsPh 3 (6)] in which the bridging ligands adopt a head-to-tail arran

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
URI: http://hdl.handle.net/1885/19318
Source: Organometallics
DOI: 10.1021/om300525p

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