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Spectroscopic and Catalytic Characterization of a Functional Fe III Fe II Biomimetic for the Active Site of Uteroferrin and Protein Cleavage

Smith, Sarah J; Peralta, Rosely A; Jovito, Rafael; Horn, Adolfo; Bortoluzzi, Adailton J; Noble, Christopher J.; Hanson, Graeme; Stranger, Robert; Jayaratne, Vidura; Cavigliasso, German; Gahan, Lawrence; Schenk, Gerhard; Nascimento, Otaciro R; Cavalett, Angélica; Bortolotto, Tiago; Razzera, Guilherme; Terenzi, Hernán; Neves, Ademir; Riley, Mark J


A mixed-valence complex, [FeIIIFeIIL1(μ-OAc)2]BF4·H2O, where the ligand H2L1 = 2-{[[3-[((bis-(pyridin-2-ylmethyl)amino)methyl)-2-hydroxy-5-methylbenzyl] (pyridin-2-ylmethyl)amino]methyl]phenol}, has been studied with a range of techniques, and, where po

CollectionsANU Research Publications
Date published: 2012
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic201711p


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