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Templated synthesis and intact coordination of a diorganotriselenane: [RuCl 2 (PPh 3 ){κ 3 - Se , N , N' -Se(mt Se ) 2 }] (mt Se = selenomethimazolyl)

Dewhurst, Rian; Hansen, Andrew; Hill, Anthony; Smith, Matthew

Description

The reaction of [RuCl2(PPh3)3] with methimazole (Hmt) under basic conditions provides the simple bis(chelate) complex [Ru(κ2-S,N-mt)2(PPh3) 2], while the selenium analogue HmtSe provides an intact coordinated diorganotriselenane [Ru{κ3-Se,N,N′-Se(mt S

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/18647
Source: Organometallics
DOI: 10.1021/om0608511

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