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Chemoenzymatic Access to Versatile Epoxyquinol Synthons

Pinkerton, David; Banwell, Martin; Willis, Anthony


The enantiomerically pure and readily available metabolites 10-12 have been converted over four simple steps Into the epoxyquinol derivatives 22-24, respectively. Compounds 23 and 24 or their Immediate precursors have been exploited In efficient total syntheses of (-)-bromoxone (ent-1), (-)-epiepoformin (ent-2), (-)-harveynone (4), (+)-panepophenanthrin (6), and (+)-hexacyclinol (9).

CollectionsANU Research Publications
Date published: 2009
Type: Journal article
Source: Organic Letters
DOI: 10.1021/ol9016657


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