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Mixed-Metal Cluster Chemistry. 29. Core Expansion and Ligand-Driven Metal Exchange at Group 6-Iridium Clusters

Usher, Alistair; Lucas, Nigel; Dalton, Gulliver; Randles , Michael; Viau, Lydie; Petrie, Simon; Stranger, Robert; Willis, Anthony; Rae, A David; Humphrey, Mark


Reactions of the tetrahedral clusters Molr3(μ-CO) 3(CO)8(η-L) (L = C5HMe4, C 5Me5) with the carbonylmetalate anions [Mo(CO) 3(η-L)]- afford the trigonal bipyramidal clusters Mo2lr3(μ3-H)(μ-CO)2(CO) 9(η-L)2 (L = C5HMe4 (3c), 74%; L = C5Me5 (3d), 55%)

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
Source: Inorganic Chemistry
DOI: 10.1021/ic061736l


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