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Naphthalimide-Tertiary Amine Derivatives as Blue-Light-Sensitive Photoinitiators

Zhang, Jing; Zivic, Nicolas; Dumur, Frederic; Xiao, Pu; Graff, Bernadette; Fouassier, Jean-Pierre; Gigmes, Didier; Lalevee, Jacques


The photochemical mechanism of the radical generation from photoinitiating systems based on 1, 8‐naphthalimide derivatives (ANDs; with tertiary amine moieties) are investigated by using various approaches including cyclic voltammetry, steady‐state photolysis, and electron spin resonance spin‐trapping techniques. It reveals that radicals can be produced from ANDs alone or ANDs/additive (e. g. iodonium salt or chloro triazine) combinations. The generated radicals and cations can initiate both...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: ChemPhotoChem
DOI: 10.1002/cptc.201800006


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