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Mixed-metal cluster chemistry. 35. Syntheses and structural studies of Mo 3 Ir 3 (μ 3 -O)(μ-CO) 3 (CO) 8 (η 5 -C 5 H 5 ) 3 , Mo 4 Ir 4 (μ-CO) 4 (CO) 9 (η 5 -C 5 H 5 ) 4 and Mo 3 Ir 5 (μ-CO) 3 (Cl)(CO) 6 (η 5 -C 5 H 5 ) 3 (η 5 -C 5 HMe 4 )**

Fu, Junhong (Nate); Moxey, Graeme; Cifuentes, Marie; Humphrey, Mark


The reaction of Ir(CO)2(h5 -C5HMe4) with Mo2Ir2(m-CO)3(CO)7(h5 -C5H5)2 affords a complex mixture from which three structurally-characterized products were obtained following thin-layer chromatography. Mo3Ir3(m3-O)(m-CO)3(CO)8(h5 -C5H5)3 (1) is Effective Atomic Number (EAN) Rule EAN-precise and possesses an edge-bridged trigonal bipyramidal core with the face-capping oxo ligand located in a Mo2Ir2 butterfly cleft in the structure. Mo4Ir4(m-CO)4(CO)9(h5 -C5H5)4 (2) possesses four...[Show more]

CollectionsANU Research Publications
Date published: 2015
Type: Journal article
Source: Journal of Organometallic Chemistry
DOI: 10.1016/j.jorganchem.2015.01.002


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