Gentleman, Alexander S.; Addicoat, Matthew A.; Dryza, Viktoras; Gascooke, Jason R.; Buntine, Mark A.; Metha, Gregory F.
The experimental and theoretical adiabatic ionization energies (IEs) of the rhodium-holmium bimetallic clusters RhHo₂On (n=0–2) have been determined using photoionization efficiency spectroscopy and density functional theory(DFT) calculations. Both sets of data show the IE of RhHo2O to be significantly lower than the values for RhHo₂ and RhHo₂O₂, which are found to be similar. This indicates that there are significant changes in electronic properties upon sequential addition of oxygen atoms to...[Show more]
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