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Structure and predissociation of the 3pσᵤD³Σᵤ⁺ Rydberg state of N₂: first extreme-ultraviolet and new near-infrared observations, with coupled-channels analysis

Lewis, B. R; Baldwin, Kenneth; Heays, Alan; Gibson, S. T; Sprengers, J. P; Ubachs, W; Fujitake, M

Description

The 3pσᵤD³Σᵤ⁺ Rydberg state of N₂ is studied experimentally using two high-resolution spectroscopic techniques. First, the forbidden D³Σᵤ⁺-X¹Σg⁺ transition is observed for the first time via the (0,0) band of ¹⁴N₂ and the (1,0) band of ¹⁵N₂, using 1 extreme-ultraviolet +1 ultraviolet two-photon-ionization laser spectroscopy. Second, the Rydberg-Rydberg transition D³Σᵤ⁺-E³Σg⁺ is studied using near-infrared diode-laser photoabsorption spectroscopy, thus extending the previous measurements of...[Show more]

CollectionsANU Research Publications
Date published: 2008-11-24
Type: Journal article
URI: http://hdl.handle.net/1885/16615
Source: The Journal of Chemical Physics
DOI: 10.1063/1.3023034

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