Structure and predissociation of the 3pσᵤD³Σᵤ⁺ Rydberg state of N₂: first extreme-ultraviolet and new near-infrared observations, with coupled-channels analysis
The 3pσᵤD³Σᵤ⁺ Rydberg state of N₂ is studied experimentally using two high-resolution spectroscopic techniques. First, the forbidden D³Σᵤ⁺-X¹Σg⁺ transition is observed for the first time via the (0,0) band of ¹⁴N₂ and the (1,0) band of ¹⁵N₂, using 1 extreme-ultraviolet +1 ultraviolet two-photon-ionization laser spectroscopy. Second, the Rydberg-Rydberg transition D³Σᵤ⁺-E³Σg⁺ is studied using near-infrared diode-laser photoabsorption spectroscopy, thus extending the previous measurements of...[Show more]
|Collections||ANU Research Publications|
|Source:||The Journal of Chemical Physics|
|01_Lewis_Structure_and_predissociation_2008.pdf||Published Version||589.23 kB||Adobe PDF|
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