Structure and predissociation of the 3pσᵤD³Σᵤ⁺ Rydberg state of N₂: first extreme-ultraviolet and new near-infrared observations, with coupled-channels analysis
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Lewis, B. R; Heays, Alan; Gibson, S. T; Sprengers, J. P; Ubachs, W; Fujitake, M; Baldwin, Kenneth
Description
The 3pσᵤD³Σᵤ⁺ Rydberg state of N₂ is studied experimentally using two high-resolution spectroscopic techniques. First, the forbidden D³Σᵤ⁺-X¹Σg⁺ transition is observed for the first time via the (0,0) band of ¹⁴N₂ and the (1,0) band of ¹⁵N₂, using 1 extreme-ultraviolet +1 ultraviolet two-photon-ionization laser spectroscopy. Second, the Rydberg-Rydberg transition D³Σᵤ⁺-E³Σg⁺ is studied using near-infrared diode-laser photoabsorption spectroscopy, thus extending the previous measurements of...[Show more]
Collections | ANU Research Publications |
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Date published: | 2008 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/16615 |
Source: | The Journal of Chemical Physics |
DOI: | 10.1063/1.3023034 |
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01_Lewis_Structure_and_predissociation_2008.pdf | Published Version | 589.23 kB | Adobe PDF | ![]() |
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