A coupled-channel model of the ³Πᵤ states of N₂: structure and interactions of the 3sσgF₃³Πᵤ and 3pπᵤG₃³Πᵤ Rydberg states
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Lewis, B. R.; Heays, Alan; Gibson, S. T.; Lefebvre-Brion, H.; Lefebvre, R.
Description
New and existing spectroscopic data on N₂, obtained using a wide variety of experimental techniques, are interpreted using a coupled-channel Schrodinger-equation (CSE) model of the structure and predissociation dynamics for the interacting Rydberg and valence states of ³Πᵤ symmetry. As a result, v>0 levels of the 3pπᵤG₃³Πᵤ ³Πᵤ Rydberg state are assigned correctly for the first time, leading to the identification of very strong perturbations in the G₃-state vibrational structure. A four-channel...[Show more]
Collections | ANU Research Publications |
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Date published: | 2008-10-24 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/16611 |
Source: | The Journal of Chemical Physics |
DOI: | 10.1063/1.2990656 |
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01_Lewis_A_coupled-channel_model_of_the_2008.pdf | Published Version | 244.17 kB | Adobe PDF | ![]() |
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