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Optical observation of the C, 3sσgF₃, and 3pπᵤG₃³Πᵤ states of N₂

Lewis, B. R; Sprengers, J. P; Ubachs, W; Stark, G; Yoshino, K; Baldwin, Kenneth


High-resolution laser-based one extreme-ultraviolet (EUV)+one UV two-photon ionization spectroscopy and EUV photoabsorption spectroscopy have been employed to study spin-forbidden ³Πᵤ-X ¹Σg⁺(v,0) transitions in ¹⁴N₂ and ¹⁵N₂. Levels of the C ³Πᵤ valence and 3sσgF₃ and 3pΠᵤG₃ ³Πᵤ Rydberg states are characterized, either through their direct optical observation, or, indirectly, through their perturbative effects on the ¹Πᵤ and ¹Σᵤ⁺ states, which are accessible in dipole-allowed transitions....[Show more]

CollectionsANU Research Publications
Type: Journal article
Source: The Journal of Chemical Physics
DOI: 10.1063/1.2990655


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