Skip navigation
Skip navigation

Selective cross-polarization in solution state nuclear magnetic resonance of scalar coupled spin 1/2 and quadrupolar nuclei

Eykyn, Thomas R.; Philp, David J.; Kuchel, Philip W.


Semiselective heteronuclear cross-polarization for achieving coherence transfer between a spin I=1/2 scalar coupled to a spin S⩾1/2 in isotropic solution is considered. The expansion of the density operator as products of irreducible tensor operators provides a compact formalism for describing cross-polarization involving scalar coupled quadrupolar nuclei. An analytical description of cross-polarization is presented in the limit of strong radio-frequency (rf) fields, with respect to the...[Show more]

CollectionsANU Research Publications
Date published: 2003-04-15
Type: Journal article
Source: The Journal of Chemical Physics
DOI: 10.1063/1.1560955


File Description SizeFormat Image
01_Eykyn_Selective_cross-polarization_2003.pdfPublished Version124.8 kBAdobe PDFThumbnail

Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  12 November 2018/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator