Skip navigation
Skip navigation

Effect of heteroatom and functionalitysubstitution on the oxidation potential of cyclicnitroxide radicals: role of electrostatics inelectrochemistry†

Zhang, Kai; Noble, Ben; Mater, Adam; Monteiro, Michael J; Coote, Michelle; Jia, Zhongfan

Description

The oxidation potential of a test set of 21 nitroxide radicals, including a number of novel compounds, has been studied experimentally in acetonitrile and correlated with theoretical calculations. It was found that both Hammett constants (σp) of the substituents on the nitroxide radicals and hyperfine splitting constants of the respective nitrogen atoms (αN) were well correlated to their experimental oxidation potentials. Theoretical calculations, carried out at the...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
URI: http://hdl.handle.net/1885/164867
Source: Physical Chemistry Chemical Physics
DOI: 10.1039/C7CP07444A
Access Rights: Open Access

Download

File Description SizeFormat Image
Effect of Heteroatom Postprint.pdf1.14 MBAdobe PDFThumbnail


Items in Open Research are protected by copyright, with all rights reserved, unless otherwise indicated.

Updated:  19 May 2020/ Responsible Officer:  University Librarian/ Page Contact:  Library Systems & Web Coordinator