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Quadratic and Cubic Optical Nonlinearities of Y-Shaped and Distorted-H-Shaped Arylalkynylruthenium Complexes

Morshedi, Mahbod; Kodikara, Mahesh; Corkery, Timothy; Hurst, Stephanie; Chavan, Sanjay; Kulasekera, Erandi; Stranger, Robert; Samoc, Marek; Van Cleuvenbergen, Stijn; Asselberghs, Inge; Clays, Koen Jan; Cifuentes, Marie; Humphrey, Mark


Straightforward syntheses of bis[bis{1,2-bis(diphenylphosphino)ethane}ruthenium]-functionalized 1,3,5-triethynylbenzene-cored complexes via a methodology employing “steric control” permit facile formation of Y-shaped Sonogashira coupling products and distorted-H-shaped homo-coupled quadrupolar products. Cyclic voltammetric data from these products reveal two reversible metal alkynyl-localized oxidation processes for all complexes. The wavelengths of the linear optical absorption maxima are...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: Chemistry - A European Journal
DOI: 10.1002/chem.201803696
Access Rights: Open Access


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