Quadratic and Cubic Optical Nonlinearities of Y-Shaped and Distorted-H-Shaped Arylalkynylruthenium Complexes
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Morshedi, Mahbod; Kodikara, Mahesh; Corkery, Timothy; Hurst, Stephanie; Chavan, Sanjay; Kulasekera, Erandi; Stranger, Robert; Samoc, Marek; Van Cleuvenbergen, Stijn; Asselberghs, Inge; Clays, Koen Jan; Cifuentes, Marie; Humphrey, Mark
Description
Straightforward syntheses of bis[bis{1,2-bis(diphenylphosphino)ethane}ruthenium]-functionalized 1,3,5-triethynylbenzene-cored complexes via a methodology employing “steric control” permit facile formation of Y-shaped Sonogashira coupling products and distorted-H-shaped homo-coupled quadrupolar products. Cyclic voltammetric data from these products reveal two reversible metal alkynyl-localized oxidation processes for all complexes. The wavelengths of the linear optical absorption maxima are...[Show more]
Collections | ANU Research Publications |
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Date published: | 2018 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/164805 |
Source: | Chemistry - A European Journal |
DOI: | 10.1002/chem.201803696 |
Access Rights: | Open Access |
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Quadratic and Cubic Optical Nonlinearities-AAM.pdf | 751.01 kB | Adobe PDF |
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