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Multihydroxy-Anthraquinone Derivatives as Free Radical and Cationic Photoinitiators of Various Photopolymerizations under Green LED

Zhang, Jing; Hill, Nicholas; Lalevée, Jacques; Fouassier, Jean-Pierre; Zhao, Jiacheng; Graff, Bernadette; Schmidt, Timothy W; Kable, Scott H; Stenzel, Martina H; Coote, Michelle; Xiao, Pu


Multihydroxy-anthraquinone derivatives [i.e., 1,2,4-trihydroxyanthraquinone (124-THAQ), 1,2,7-trihydroxyanthraquinone (127-THAQ), and 1,2,5,8-tetrahydroxyanthraquinone (1258-THAQ)] can interact with various additives [e.g., iodonium salt, tertiary amine, N-vinylcarbazole, and 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine] under household green LED irradiation to generate active species (cations and radicals). The relevant photochemical mechanism is investigated using quantum...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: Macromolecular Rapid Communications
DOI: 10.1002/marc.201800172
Access Rights: Open Access


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