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Experimental evidence for long-range stabilizing and destabilizing interactions between charge and radical sites in distonic ions

Marshall, David L.; Gryn'ova, Ganna; Poad, Berwyck L. J.; Bottle, Steven E.; Trevitt, Adam J.; Coote, Michelle; Blanksby, Stephen J.

Description

Polarizable radical sites in distonic radical anions are stabilized by ostensibly remote negative charges. Computational evidence suggests bond dissociation energies of closed-shell precursors are significantly lowered by through-space interactions with a proximate negative charge, however direct experimental confirmation has proved challenging. Herein, we exploit two complementary tandem mass spectrometry strategies to probe the influence of a remote charge on the stability of nitroxyl...[Show more]

CollectionsANU Research Publications
Date published: 2019
Type: Journal article
URI: http://hdl.handle.net/1885/164654
Source: International Journal of Mass Spectrometry
DOI: 10.1016/j.ijms.2018.10.031
Access Rights: Open Access

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