Linear and Third-Order Nonlinear Optical Properties of Fe(n5-C5Me5)(k2-dppe)- and trans-Ru(k2-dppe)2-Alkynyl Complexes Containing 2-Fluorenyl End Groups
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Triadon, Amedee; Grelaud, Guillaume; Richy, Nicolas; Mongin, Olivier; Moxey, Graeme; Dixon, M. Isabelle; Yang, Xinwei; Wang, Genmiao; Barlow, Adam; Joelle, Rault-Berthelot; Cifuentes, Marie; Humphrey, Mark; Paul, Frederic
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The synthesis and characterization of a set of redox-active iron and ruthenium alkynyl complexes of general formula [[M]Cl(1–p){C≡CC6H5–m(C≡CFlu)m}(1+p)][PF6]n are reported (n = 0–1; m = 1–2; [M] = [Fe(η5-C5Me5)(κ2-dppe)] and p = 1 or [M] = [trans-Ru(κ2-dppe)2] and p = 0–1). The linear and third-order nonlinear optical properties of these new organometallic complexes featuring phenylalkynyl ligands functionalized by 2-fluorenyl (Flu) groups were studied in their stable redox states. Their first...[Show more]
dc.contributor.author | Triadon, Amedee | |
---|---|---|
dc.contributor.author | Grelaud, Guillaume | |
dc.contributor.author | Richy, Nicolas | |
dc.contributor.author | Mongin, Olivier | |
dc.contributor.author | Moxey, Graeme | |
dc.contributor.author | Dixon, M. Isabelle | |
dc.contributor.author | Yang, Xinwei | |
dc.contributor.author | Wang, Genmiao | |
dc.contributor.author | Barlow, Adam | |
dc.contributor.author | Joelle, Rault-Berthelot | |
dc.contributor.author | Cifuentes, Marie | |
dc.contributor.author | Humphrey, Mark | |
dc.contributor.author | Paul, Frederic | |
dc.date.accessioned | 2019-07-08T05:17:12Z | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.uri | http://hdl.handle.net/1885/164390 | |
dc.description.abstract | The synthesis and characterization of a set of redox-active iron and ruthenium alkynyl complexes of general formula [[M]Cl(1–p){C≡CC6H5–m(C≡CFlu)m}(1+p)][PF6]n are reported (n = 0–1; m = 1–2; [M] = [Fe(η5-C5Me5)(κ2-dppe)] and p = 1 or [M] = [trans-Ru(κ2-dppe)2] and p = 0–1). The linear and third-order nonlinear optical properties of these new organometallic complexes featuring phenylalkynyl ligands functionalized by 2-fluorenyl (Flu) groups were studied in their stable redox states. Their first electronic transitions are assigned with the help of DFT calculations. We show here that these compounds possess significant third-order NLO responses in the near-IR range for molecules of their size. In particular, the remarkably large 2PA activities of the new Ru(II) compounds in the 600–800 nm range (Z-scan) make them attractive nonlinear chromophores. Structure–property studies emphasize the importance of para- versus meta-connection of the 2-fluorenylethynyl units on the phenylalkynyl core and reveal that upon progressing from mono- to bis-alkynyl complexes a further increase of the 2PA cross section can be obtained while maintaining linear transparency in the visible range. | |
dc.format.mimetype | application/pdf | |
dc.language.iso | en_AU | |
dc.publisher | American Chemical Society | |
dc.rights | © 2018 American Chemical Society | |
dc.source | Organometallics | |
dc.source.uri | https://pubs.acs.org/doi/10.1021/acs.organomet.8b00229 | |
dc.title | Linear and Third-Order Nonlinear Optical Properties of Fe(n5-C5Me5)(k2-dppe)- and trans-Ru(k2-dppe)2-Alkynyl Complexes Containing 2-Fluorenyl End Groups | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 37 | |
dc.date.issued | 2018 | |
local.identifier.absfor | 030303 - Optical Properties of Materials | |
local.identifier.ariespublication | a383154xPUB10466 | |
local.type.status | Accepted Version | |
local.contributor.affiliation | Triadon, Amedee, Université de Rennes | |
local.contributor.affiliation | Grelaud, Guillaume, College of Science, ANU | |
local.contributor.affiliation | Richy, Nicolas, Université de Rennes | |
local.contributor.affiliation | Mongin, Olivier, Universite Rennes | |
local.contributor.affiliation | Moxey, Graeme, College of Science, ANU | |
local.contributor.affiliation | Dixon, M. Isabelle, University of Toulouse | |
local.contributor.affiliation | Yang, Xinwei, College of Science, ANU | |
local.contributor.affiliation | Wang, Genmiao, College of Science, ANU | |
local.contributor.affiliation | Barlow, Adam, College of Science, ANU | |
local.contributor.affiliation | Joelle, Rault-Berthelot, University of Rennes | |
local.contributor.affiliation | Cifuentes, Marie, College of Science, ANU | |
local.contributor.affiliation | Humphrey, Mark, College of Science, ANU | |
local.contributor.affiliation | Paul, Frederic, Universite de Rennes | |
local.bibliographicCitation.issue | 14 | |
local.bibliographicCitation.startpage | 2245 | |
local.bibliographicCitation.lastpage | 2262 | |
local.identifier.doi | 10.1021/acs.organomet.8b00229 | |
local.identifier.absseo | 970103 - Expanding Knowledge in the Chemical Sciences | |
dc.date.updated | 2019-03-31T07:17:58Z | |
local.identifier.scopusID | 2-s2.0-85050457046 | |
dcterms.accessRights | Open Access | |
dc.provenance | https://v2.sherpa.ac.uk/id/publication/7795..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 8/11/2021). This document is the unedited Author’s version of a Submitted Work that was subsequently accepted for publication in [Organometallics], copyright © American Chemical Society after peer review. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.organomet.8b00229 | |
Collections | ANU Research Publications |
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