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Linear and Third-Order Nonlinear Optical Properties of Fe(n5-C5Me5)(k2-dppe)- and trans-Ru(k2-dppe)2-Alkynyl Complexes Containing 2-Fluorenyl End Groups

Triadon, Amedee; Grelaud, Guillaume; Richy, Nicolas; Mongin, Olivier; Moxey, Graeme; Dixon, M. Isabelle; Yang, Xinwei; Wang, Genmiao; Barlow, Adam; Joelle, Rault-Berthelot; Cifuentes, Marie; Humphrey, Mark; Paul, Frederic

Description

The synthesis and characterization of a set of redox-active iron and ruthenium alkynyl complexes of general formula [[M]Cl(1–p){C≡CC6H5–m(C≡CFlu)m}(1+p)][PF6]n are reported (n = 0–1; m = 1–2; [M] = [Fe(η5-C5Me5)(κ2-dppe)] and p = 1 or [M] = [trans-Ru(κ2-dppe)2] and p = 0–1). The linear and third-order nonlinear optical properties of these new organometallic complexes featuring phenylalkynyl ligands functionalized by 2-fluorenyl (Flu) groups were studied in their stable redox states. Their first...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
URI: http://hdl.handle.net/1885/164390
Source: Organometallics
DOI: 10.1021/acs.organomet.8b00229

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