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Linear Optical, Quadratic and Cubic Nonlinear Optical, Electrochemical, and Theoretical Studies of "Rigid-Rod" Bis-Alkynyl Ruthenium Complexes

Babgi, Bandar; Kodikara, Mahesh; Morshedi, Mahbod; Wang, Huan; Quintana, Cristobal; Schwich, Torsten; Moxey, Graeme; Van Steerteghem, Nick; Clays, Koen Jan; Stranger, Robert; Cifuentes, Marie; Humphrey, Mark


The syntheses of oligo(p‐phenylene ethynylene)s (OPEs) end‐functionalized by a nitro acceptor group and with a ligated ruthenium unit at varying locations in the OPE chain, namely, trans‐[Ru{(C≡C‐1,4‐C6H4)nNO2}(C≡CR)(dppe)2] (dppe=1,2‐bis(diphenylphosphino)ethane; n=1, R=1,4‐C6H4C≡C‐1,4‐C6H4C≡CPh, 1,4‐C6H4NEt2; n=2, R=Ph, 1,4‐C6H4C≡CPh, 1,4‐C6H4C≡C‐1,4‐C6H4C≡CPh, 1,4‐C6H4NO2, 1,4‐C6H4NEt2; n=3, R=Ph, 1,4‐C6H4C≡CPh), are reported. Their electrochemical properties were assessed by cyclic...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: ChemPlusChem
DOI: 10.1002/cplu.201800093
Access Rights: Open Access


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