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Bimetallic Complexes of Group 8, 9, and 11 Metals Bridged by RB(NCH₂PPh₂)₂C₆H₄ (R = H, 4-C₆H₄X; X = H, Me, F) Ligands

Sung, Simon; Ang, Angelina; Hill, Anthony; Ma, Chenxi; Kong, Richard; Ward, James; Young, Rowan D.


The 1‐aryl‐2,1,3‐diazaboroles ArB(NCH2PPh2)2C6H4 (Ar = C6H5 1a, 4‐MeC6H4 1b, 4‐FC6H4 1c) result from the reactions of ArBCl2 with 1,2‐(NHCH2PPh2)2C6H4 in the presence of triethylamine. The reactions of these new proligands in addition to the parent diazaborole HB(NCH2PPh2)2C6H4 (4) with a range of metal precursors [Ru2(µ‐Cl)2Cl2(η6‐1,3,5‐Me3C6H3)2], [M2(µ‐Cl)2Cl2(η5‐C5Me5)2], [M2(µ‐Cl)2(η4‐C8H12)2] (M = Rh, Ir) and [AuCl(SC4H8)] have been explored. Rather than forming chelating, bidentate...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: European Journal of Inorganic Chemistry
DOI: 10.1002/ejic.201800448


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