Observation of a new electronic state of CO perturbing W¹Π1(v=1)
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Heays, Alan; Eidelsberg, M.; Stark, G.; Lemaire, J. L.; Gavilan, L.; Federman, S. R.; Lewis, B. R.; Lyons, J. R.; de Oliveira, N.; Joyeux, D.
Description
We observe photoabsorption of the W(1) ← X(0) band in five carbon monoxide isotopologues with a vacuum-ultraviolet Fourier-transform spectrometer and a synchrotron radiation source. We deduce transition energies, integrated cross sections, and natural linewidths of the observed rotational transitions and find a perturbation affecting these. Following a deperturbation analysis of all five isotopologues, the perturbing state is assigned to the v = 0 level of a previously unobserved (1)Π state...[Show more]
Collections | ANU Research Publications |
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Date published: | 2014-10-14 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/16120 |
Source: | The Journal of Chemical Physics |
DOI: | 10.1063/1.4897326 |
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01_Heays_Observation_of_a_new_2014.pdf | Published Version | 890.52 kB | Adobe PDF | ![]() |
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