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Syntheses of Structurally and Stereochemically Varied Forms of C7N Aminocyclitol Derivatives from Enzymatically Derived and Homochiral cis-1,2-Dihydrocatechols

Dlugosch, Michael; Ma, Xinghua; Yang, Shuxin; Banwell, Martin; Ma, Chenxi; Ward, Jas; Carr, Paul D


The structurally and stereoisomerically varied C7N aminocyclitol derivatives 2-4 have been prepared, using a versatile and flexible range of protocols, from the cis-1,2-dihydrocatechols 5 and 6, homochiral metabolites derived from the whole-cell biotransformation of the corresponding halobenzene. Reaction sequences that enable syntheses of the enantiomeric forms of these derivatives have also been established.

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: Organic Letters
DOI: 10.1021/acs.orglett.8b03149
Access Rights: Open Access


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