Bis(alkylidynyl)tellurides and ditellurides
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Frogley, Benjamin; Hill, Anthony; Manzano, Richard; Sharma, Manab
Description
The tellurocarbonylates [M(CTe)(CO)(2)(Tp*)](-) (M = Mo, W; obtained from [M(equivalent to CBr)(CO)(2)(Tp*)] and Li2Te or [M(equivalent to CLi)(CO)(2)(Tp*)] and Te) react with an additional equivalent of [M(equivalent to CBr)(CO)(2)(Tp*)] to give bis(alkylidynyl) tellurides, [M-2(mu-CTeC)(CO)(4)(Tp*)(2)], whilst oxidation with [Fe(eta-C5H5)(2)]PF6 affords the corresponding ditellurides [M-2(mu-CTe2C)(CO)(4)(Tp*)(2)]. The unprecedented M equivalent to CTeC equivalent to M and M equivalent to...[Show more]
Collections | ANU Research Publications |
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Date published: | 2018 |
Type: | Journal article |
URI: | http://hdl.handle.net/1885/160556 |
Source: | Chemical Communications |
DOI: | 10.1039/c7cc08776d |
Access Rights: | Open Access |
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10.1039_C7CC08776D.pdf | 1.08 MB | Adobe PDF | ![]() |
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