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Bis(alkylidynyl)tellurides and ditellurides

Frogley, Benjamin; Hill, Anthony; Manzano, Richard; Sharma, Manab


The tellurocarbonylates [M(CTe)(CO)(2)(Tp*)](-) (M = Mo, W; obtained from [M(equivalent to CBr)(CO)(2)(Tp*)] and Li2Te or [M(equivalent to CLi)(CO)(2)(Tp*)] and Te) react with an additional equivalent of [M(equivalent to CBr)(CO)(2)(Tp*)] to give bis(alkylidynyl) tellurides, [M-2(mu-CTeC)(CO)(4)(Tp*)(2)], whilst oxidation with [Fe(eta-C5H5)(2)]PF6 affords the corresponding ditellurides [M-2(mu-CTe2C)(CO)(4)(Tp*)(2)]. The unprecedented M equivalent to CTeC equivalent to M and M equivalent to...[Show more]

CollectionsANU Research Publications
Date published: 2018
Type: Journal article
Source: Chemical Communications
DOI: 10.1039/c7cc08776d
Access Rights: Open Access


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