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Relations between Rydberg-valence interactions in the O₂ molecule

Lewis, B. R.; Gibson, S. T.; Banerjee, S. S.; Lefebvre-Brion, H.


Using a single-configuration formulation, analytical expressions are derived for the (X²Πg) nsσg, npπu, and npσu Rydberg-valence interaction matrix elements in O₂. In addition, new results from diabatic, coupled-channel deperturbations of experimental data dependent on these interactions are reported for n=3 and 4. Using these results, the large differences in magnitude between the Rydberg-valence couplings for the constituent states of the npπuRydberg complex that are predicted by the...[Show more]

CollectionsANU Research Publications
Date published: 2000-08-08
Type: Journal article
Source: The Journal of Chemical Physics
DOI: 10.1063/1.482035


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