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4-Halogeno-3,5-dimethyl-1H-pyrazole-1-carbodithioates: Versatile reversible addition fragmentation chain transfer agents with broad applicability

Gardiner, James; Martinez-Botella, Ivan; Kohl, Thomas M.; Krstina, Julia; Moad, Graeme; Tyrell, Jason; Coote, Michelle; Tsanaktsidis, John


Pyrazole-based dithiocarbamates are versatile reversible addition fragmentation chain transfer (RAFT) agents that provide molar mass and dispersity (D) control over the radical polymerization of both more and less activated monomers (MAMs and LAMs). In this paper we report on theoretical and experimental findings demonstrating that their activity as RAFT agents can be significantly enhanced by introducing electron-withdrawing substituents to the pyrazole ring. This enhancement is most...[Show more]

CollectionsANU Research Publications
Date published: 2017
Type: Journal article
Source: Polymer International
DOI: 10.1002/pi.5423
Access Rights: Open Access


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