Accessing Polyoxygenated Dibenzofurans via the Union of Phenols and o-Benzoquinones: Rapid Syntheses of Metabolites Isolated from Ribes takare
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The construction of polyoxygenated dibenzo[b,d]furan frameworks from the union of substituted phenols/naphthols and o-benzoquinones via a Michael-oxidation-oxa-Michael cascade is reported. The power of this transformation is demonstrated in the generation of a library of highly substituted dibenzofurans, featuring specifically substituted molecules containing broad ranges of functionality. The utility of this method is showcased in the total syntheses of two dibenzofurans isolated from Ribes...[Show more]
dc.contributor.author | Zhang, Meng | |
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dc.contributor.author | Barrow, Russell | |
dc.date.accessioned | 2019-04-08T02:28:02Z | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.uri | http://hdl.handle.net/1885/159296 | |
dc.description.abstract | The construction of polyoxygenated dibenzo[b,d]furan frameworks from the union of substituted phenols/naphthols and o-benzoquinones via a Michael-oxidation-oxa-Michael cascade is reported. The power of this transformation is demonstrated in the generation of a library of highly substituted dibenzofurans, featuring specifically substituted molecules containing broad ranges of functionality. The utility of this method is showcased in the total syntheses of two dibenzofurans isolated from Ribes takare, assembling the carbon scaffold of both natural products in one operation. | |
dc.format.mimetype | application/pdf | |
dc.language.iso | en_AU | |
dc.publisher | American Chemical Society | |
dc.source | Organic Letters | |
dc.title | Accessing Polyoxygenated Dibenzofurans via the Union of Phenols and o-Benzoquinones: Rapid Syntheses of Metabolites Isolated from Ribes takare | |
dc.type | Journal article | |
local.description.notes | Imported from ARIES | |
local.identifier.citationvolume | 19 | |
dc.date.issued | 2017 | |
local.identifier.absfor | 030503 - Organic Chemical Synthesis | |
local.identifier.ariespublication | a383154xPUB7003 | |
local.type.status | Published Version | |
local.contributor.affiliation | Zhang, Meng, College of Science, ANU | |
local.contributor.affiliation | Barrow, Russell, College of Science, ANU | |
local.description.embargo | 2039-12-31 | |
local.bibliographicCitation.issue | 9 | |
local.identifier.doi | 10.1021/acs.orglett.7b00840 | |
dc.date.updated | 2019-03-12T07:20:54Z | |
local.identifier.scopusID | 2-s2.0-85019047658 | |
local.identifier.thomsonID | 000401044500027 | |
dc.provenance | Journal: Organic Letters (ISSN: 1523-7060, ESSN: 1523-7052) RoMEO: This is a RoMEO white journal Paid OA: A paid open access option is available for this journal. Author's Pre-print: grey tick subject to Restrictions below, author can archive pre-print (ie pre-refereeing) Restrictions: Must obtain written permission from Editor Must not violate ACS ethical Guidelines Author's Post-print: grey tick subject to Restrictions below, author can archive post-print (ie final draft post-refereeing) Restrictions: If mandated by funding agency or employer/ institution If mandated to deposit before 12 months, must obtain waiver from Institution/Funding agency or use AuthorChoice 12 months embargo Publisher's Version/PDF: cross author cannot archive publisher's | |
Collections | ANU Research Publications |
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